Abstract |
Ultrasonic Cavitational Technologies
N.V.Malykh (Institute of Thermophysics
SD RAS, Novosibirsk, Russia); A.O.Kuzmin (Institute of Catalysis SD RAS,
Novosibirsk, Russia)
e-mail:
Malykh@itp.nsc.ru
Experimentally
investigated in this paper, is the process of an ultrasonic cavitation in
various liquids, including loaded with solid particles. The effect of growth of
particle subdivision degree and acceleration of chemical reaction is obtained.
The optimal power and frequencies of ultrasonic field are determined. A
frequency is chosen to be equal to a resonance frequency of bubbles
commensurable with a current pore size on solid particle surface. The paper
pioneers in synthesizing the expensive catalysts, such as
molybdenicvanadicphosphoic heteropolyacids.The production time is reduced from
some days to some hours. Investigations were performed too of phenol oxidation
in aqueous solutions by cavitation and the way for the optimization was
suggested with respect to decrease the energy consumption and the time of
solution processing. The efficiency of cavitation is proved also for
decomposition of the solutions of 1,1 dimethilhydrozine. Cleaning of aqueous
solutions from organic contaminants, ecologically clean chemical technologies
gain in importance all over the world. Besides the applied aspects, this
problem is closely connected with the nonlinear wave dynamics of polyphase
medium and supplements those part of investigation, where it is quite difficult
to describe the processes mathematically.
Section
: 11